課程介紹
Course Description
本課程先複習熱力學三大定律及各種熱力學函數，例如熱容量,entropy,焓及自由能等，從統計熱力學解釋entropy之微觀意義;熱力學函數的基本數學;介紹熱力學之平衡觀念及單元系統的相轉變o再討論氣體的混合，討論理想與真實溶液之性質，雙元相圖與自由能之關係，化學反應之平衡觀念，特別以固態材料系統為對象，探討其化學反應及相轉變所需考量之熱力學觀念。
This course will review the three laws of thermodynamics and thermodynamic functions, such as heat capacity, entropy, enthalpy, free energy. And we will explain the microscopic meaning of entropy by statistical thermodynamics, the basic mathematics for derivation of some important thermodynamic equations, the concepts of thermodynamic equilibrium for the phase transition of unary system.Thermodynamics of gas phase mixing, properties of ideal and real solutions of condensed matter, the relationship between binary phase diagram and Gibbs free energy curves, and the concepts of reaction equilibrium will be explained.Thermodynamic concepts for phase transitionsand chemicalreaction are discussed.

教學進度
Syllabus

【第1週】	Ch.1~8 Review of fundamental Thermodynamics(I):
	1.Scope of Materials Thermodynamics 2.Laws of Thermodynamics 3.Definitions of thermodynamic functions and some important parameters 4.Variation of V, S, H, G as a function of T, P.
【第2週】	Ch.1~8 Review of fundamental Thermodynamics(II):
	1.Calculation of S, H, G and S, H, G for temperature changes at constant P 2.Application of Gibbs-Helmholtz Eq., Clapeyron Eq., Clausius-Clapeyron Eq 3.G(T,P) for a single phase substance and two-phases equilibrium.
【第3週】	Ch.1~8 Review of fundamental Thermodynamics(II):
	1.Thermodynamic Properties of Ideal Gas and Ideal Gas Mixture 2.Thermodynamic Treatment of Nonideal Gas (Real Gas)
【第4週】	Ch.9 Behavior of solutions(I):
	1.Raoult’s law and Henry’s law 2.Activity of a component in solution 3.Gibbs-Duhem equation 4.Relation between G and  of binary solution 5.Relation between ai,and ,GM 6.Method of graphical determination of   from  GM
【第5週】	Ch.9 Behavior of solutions(II):
	1.Properties of ideal solution 2.Nonideal solution 3.Application of Gibbs-Duhem equation (1-2).
【第6週】	Ch.9 Behavior of solutions(III):
	1.Apllication of Gibbs-Duhem equation(3) 2.Regular solution 3.Non-regular solution
【第7週】	Ch.9 Behavior of solutions(IV):
	1.Quasi-chemical model of solutions 2.Calculation examples.
【第8週】	Ch.10 Binary phase Diagrams and G M (X B ) curves(I):
	1. G M (X B ) curve of a homogeneous solution 2. G M (X B ) curve of a regular solution 3.Citerior for phase stability in regular solution.
【第9週】	1.Mid-term exam
	2. Ch.10 Binary phase Diagrams and G M (X B ) curves(II):   Standard states and two-phases equilibrium.
【第10週】	Ch.10 Binary phase Diagrams and G M (X B ) curves(III):
	1.Isomorphous phase diagram 2.Binary phase diagrams with liquid and solid exhibiting regular solution
【第11週】	Ch.10 Binary phase Diagrams and G M (X B ) curves(IV):
	1.Eutectic phase diagrams 2.Monotectic phase diagram
【第12週】	Ch.11 Reactions involving gases(I):
	1.Reaction equilibrium in gas mixture and equilibrium constant 2.Effect of temperature on K p 3.Effect of total pressure on K p .
【 第13週】	Ch.11 Reactions involving gases(II):
	1.Reaction equilibrium in SO 2 -SO 3 -O 2 system 2.To keep a constant p O2 through gas mixture of SO 2 /SO 3 , CO/CO 2 ,H 2 /H 2 O.
【第14週】	Ch.11 Reactions involving gases(III): Calculation examples.
	Ch.12 Reactions involving gases and pure condensed phases(I): 1.Reaction equilibrium in a system containing pure condensed phases and gas phases. 2.Variation of “Standard Gibbs free energy change” with T.
【第15週】	Ch.12 Reactions involving gases and pure condensed phases(II):
	1.Ellingham Diagrams 2.Stability of metals and metal-oxides.
【第16週】	Ch.12 Reactions involving gases and pure condensed phases(III):
	1.Effect of phase transition 2.Stability of oxides in H 2 /H 2 O gas mixtures 3.Nomographic scale of H 2 /H 2 O
【第17週】	Ch.12 Reactions involving gases and pure condensed phases(IV):
	1.Stability of oxides in CO/CO 2 gas mixtures 2.Upper limit of (p CO /p CO2 ) at a fixed T 3.Calculation examples. 材料熱力學1.2講義 更新 !